| dc.contributor.advisor | gottardo, christine | |
| dc.contributor.author | boissy, christine | |
| dc.date | 2017 | |
| dc.date.accessioned | 2018-02-22t18:21:31z | |
| dc.date.available | 2018-02-22t18:21:31z | |
| dc.date.issued | 2017 | |
| dc.identifier.uri | https://knowledgecommons.lakeheadu.ca/handle/2453/4101 | |
| dc.description.abstract | a variety of room temperature ionic liquids have been synthesized and applied to various
reactions. four of these ionic liquids were prepared in a chiral manner: [1-butyl-3-
methylimidazolium][l-lactate], [1-butyl-3-methylimidazolium][d-lactate], [1-butyl-3-
methylimidazolium][(1s)(+)-10-camphorsulfonate], and [1-butyl-3-methylimidazolium][(1r)(-)-10-
camphorsulfonate]. these chiral ionic liquids were used as solvents in asymmetric spiroacetal
cyclizations and truce-smiles rearrangements to induce chirality to the reactions.
additionally, four other ionic liquids were synthesized for use in electrochemical
experiments: [1-butyl-3-methylimidazolium][bf4], [1-butyl-3-methylimidazolium][pf6], [1-butyl-3-
methylimidazolium][scn] and [1-butyl-3-methylimidazolium][tau]. these ionic liquids were used
as an additive during electrochemical nickel deposition and dissolution to improve the effect of
the watts solution. | en_us |
| dc.language.iso | en_us | en_us |
| dc.subject | synthetic applications of rtils | en_us |
| dc.subject | asymmetric synthesis | en_us |
| dc.subject | asymmetric spiroacetal cyclization | en_us |
| dc.subject | truce-smiles rearrangement | en_us |
| dc.subject | electrodeposition/dissolution of nickel in rtil | en_us |
| dc.title | synthesis and applications of room temperature ionic liquids | en_us |
| dc.type | thesis | |
| etd.degree.name | master of science | en_us |
| etd.degree.level | master | en_us |
| etd.degree.discipline | chemistry | en_us |
| etd.degree.grantor | 阿根廷vs墨西哥竞猜
| en_us |
